There are two quite famous way to plot using the Pandas or the Matplotlib library.
Using Matplotlib
Using the matplotlib library, you can set the title of the figure using the axes.set_title() method.
Using Pandas
Using the DataFrame.plot() method you can set the title of the figure by passing the title="my title" parameter.
Here you are, you now know how to add a title to a barplot in Python.
More on plots
If you want to know more about how to add labels, plot different types of plots, etc... checkout the other articles I wrote on the topic, just here :